Triptycene and its derivatives are a class of compounds with a unique three-dimensional rigid structure and are widely used in many fields such as molecular machines, materials chemistry, and supramolecular chemistry [1]. Researcher Chen Chuanfeng from the Institute of Chemistry, Chinese Academy of Sciences, successfully synthesized a new host molecule based on triptycene - triptycene crown ether. The characteristics are as follows:
Figure 1 Structural formula of triptycene crown ether[1,2]
References
- Ying Han, Zheng Meng, Ying-Xian Ma, and Chuan-Feng Chen. Acc. Chem. Res. 2014, 47, 2026-2040.
- Zheng Meng, Ying Han, Li-Na Wang, Jun-Feng Xiang, Sheng-Gui He, Chuan-Feng Chen. J. Am. Chem. Soc. 2015, 137, 9739-9745.
Bailingwei exclusively sells the main molecule of triptycene crown ether, the scientific research result of researcher Chen Chuanfeng.
Introduction to the research group: Researcher Chen Chuanfeng’s research group is committed to the establishment and development of synthetic host molecular systems with structural and functional characteristics, and research on the design, synthesis and application of organic functional molecules, including calixarene chemistry and ultrasonic new synthetic hosts based on styrene. A series of research achievements have been made in molecular chemistry, multi-hydrogen bonded molecular assembly, and the synthesis and application of helical chiral molecules (helical foldamers, helixes) (molecular recognition and cell imaging, molecular assembly, organic light-emitting materials, asymmetric catalysis), etc. Results.
Triptylene-derived macrotricyclic host
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- A new type of synthetic macrocyclic host molecule, which combines a rigid triptycene fragment with a flexible crown ether chain, contains a central cavity and two crown ether cavities.
- It can complex a variety of organic and inorganic guests, such as bipyridinium salts, ammonium salts, metal ions, etc.
- Various assemblies with special structures and functions can be formed.
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- A new type of tweezer-shaped macrocyclic host molecule, which organically combines two dibenzo-[24][24]-crown-8 fragments are organically combined by triptycene, containing three identical crown ether cavities.
- It can complex three guest molecules at the same time and can be used to construct assemblies with special structures and functions such as catenanes and molecular machines.
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100mg, 500mg
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