Organometallic chemistry focuses on the synthesis, structure, reaction, properties and applications of metal-organic compounds, and plays an important role in promoting the development of human society. Metal-organic compounds are complexes composed of a central metal atom and ligands surrounding the metal atom. Carbolong Complexes are a planar conjugated carbon chain (carbon number ≥ 7) through at least 3 carbon-metal atoms. A compound formed by bonding a transition metal together. In 2013, Professor Xia Haiping's research group synthesized and named this type of compound for the first time, and developed a series of original, unique structures and excellent performance carbolong complexes. They are rich in reactivity and can be modified through pre-modification and post-derivatization. A series of functional molecules can be obtained, which can be used in fields such as light energy conversion, biomedicine, homogeneous catalysis, and oxygen activation.
Bailingwei exclusively provides some of the carbonium complexes developed by Professor Xia Haiping’s research group, and can also provide a variety of metal-organic chemistry supporting products:

Complete range: covering three major series: metal catalysts, metal precursors for synthesis, and ligands, commonly used organometallic reagents, synthesis reagents, ultra-dry solvents, nuclear magnetic solvents and commonly used instrument consumables;
Product frontier: We can provide new metal-organic complexes and synthetic reagents that are transformed from the scientific research results of experts and scholars in this field;
Quality assurance: high purity, strict quality control, and stable batch quality.

Recommended products
Product name CAS Item number
8C Carbolong complex, 95% 1667743-98-7 9307661
12C Carbolong complex, 95% 2917610-83-2 9307662
Carbolong peroxo complex, 95% 2244156-01-0 9307663
Os-Cu Carbolong complex, 95% 2225872-98-8 9307664
Phenanthroline-Carbolong, 95% N/A 9307665

 

metal catalyst

Product name CAS Item number
Dichlorobis(triphenylphosphine)palladium(II), 98% 13965-03-2 242195
Dicobalt octacarbonyl, 95% 10210-68-1 533379
2,6-Diisopropyl-phenyl-acenaphthoimidazolylidene-N-heterocycliccarbene-palladium chloride-3-chloropyridine complex, 98% 1349182-65-5 9187355

 

metal precursor
Product name CAS Item number
Titanium(IV) chloride, 1 M solution in dichloromethane, J&KSeal 7550-45-0 459124
Vanadium(V) oxide, 99%, for synthesis 1314-62-1 972308
Zinc chloride, 98%, for analysis 7646-85-7 975486

 

Ligand
Product name CAS Item number
(+)-1,2-Bis((2S,5S)-2,5-diphenylphospholano)ethane, min. 98% (S,S)-Ph-BPE 824395-67-7 15-0474
(4R,5R)-(-)-2,2-Dimethyl-4,5-bis((diphenylphosphino)methyl)-1,3-dioxolane, 98% 32305-98-9 453464
Triphenylphosphine, 99%, Cl:≤30 ppm 603-35-0 993263

 

Azo and Diazo
Product name CAS Item number
Ethyl diazoacetoacetate, 98% 2009-97-4 460520
Ethyl diazoacetate, 95% 623-73-4 282677

 

molecular building blocks
Product name CAS Item number
Glycolic acid, 99% 79-14-1 147016
3-Pentyn-1-ol, 98% 10229-10-4 571781
3-Phenyl-1-propyne, 97%, stabilized 10147-11-2 235212

 

Organometallic reagents
Product name CAS Item number
3,5-Dimethylphenylmagnesium bromide, 0.5 M solution in THF 34696-73-6 911858
n-Butyllithium, 1.6 M solution in hexanes, J&KSeal 109-72-8 274232
Vinylmagnesium bromide, 1.0 M solution in THF, J&KSeal 1826-67-1 309166

 

Synthetic reagents
Product name CAS Item number
Potassium tert-butoxide, 1.0 M solution in THF, J&KSeal 865-47-4 962820
Titanium(IV) isopropoxide, 98% 546-68-9 162947
1,5,7-Triazabicyclo[4.4.0]dec-5-ene, 98% 5807-14-7 478441

 

General product
Product name CAS Item number
Potassium carbonate, 99% 584-08-7 212583
Sodium sulfate, 99%, anhydrous, for residue analysis 7757-82-6 940131
Dimethyl sulfoxide-d6, N/A, 99.8 atom%D, contains 0.03% v/v TMS 2206-27-1 182473
By 向阳 翟

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