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Sku 45-0115-250MG
STREM
| Technical Notes: 1.Rhodium catalyzed contrasteric regiocontrolled hydrogenative couplings of nonsymmetric 1,3 diynes to ethyl glyoxalate 2.Rhodium catalyzed reductive Mannich coupling of vinyl ketones to N-Sulfonylimines mediated by hydrogen 3.Rhodium catalyzed asymmetric synthesis of Sitagliptin 4.Rhodium catalyzed asymmetric hydrogenation of tetrasubstituted a, ß unsaturated ketones References: 1.Organometallics, 2007. 26, 3860. 2.J. Org. Chem., 2007. 72, 5843. 3.J.Am. Chem. Soc.. 2009, 131, 8798. 4.Org. Lott, 2012, 14. 1038. |
