Technical Notes: 1.Useful catalyst for the Diels-Alder reaction. 2.Excellent catalyst for the Friedel-Crafts acylations in ionic liquids, or solvent free. 3.Active catalyst for the ring- opening of cyclopropanes. 4.Used in the asymmetric Friedel-Crafts reaction of pyrroles and acrylates. References: 1. Chem. Lett., 1995, 24, 307. 2.Chem. Commun., 2004, 1368. 3.Org. Lett., 2009, 1 1, 3770. 4.Org. Lett. 2010, 12, 1136. |
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