(11bS)-4-Oxide-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-2,6-bis(2,3,4,5,6-pentafluorophenyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee)

Name: (11bS)-4-Oxide-8,9,10,11,12,13,14,15-octahydro-4-hydroxy-2,6-bis(2,3,4,5,6-pentafluorophenyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee)
Brand: STREM
SKU: 15-0569-25MG
Price: 115.0 USD
Availability: InStock

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Sku 15-0569-25MG

Vendor: STREM

Description

Technical Notes：
1.Chiral Brønsted acid catalysis for enantioselective Hosomi-Sakurai reaction of imines with allyltrimethylsilane .
2.Chiral Brønsted acid catalysis for stereoselective Mannich-type reactions of in situ generated C-alkynyl imines with ß-keto esters.
3.Chiral Brønsted acid catalysis for Mannich-type reaction of N-Boc-iminium intermediates, generated in situ from N-Boc- aminals.
References:
1. Org. Lett., 2011, 13, 2126.
2.Angew. Chem. Int. Ed. 2013, 52, 1 1509. 3.Tetrahedron, 2016, 72, 3687.