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Sku 07-1411-50MG
STREM
Technical Notes:
1.Ligand used in the Ru- and Cu-catalyzed enantios elective propargylic alkylation of propargylic alcohols with ß-ketoesters [1] and ß-keto phosphonates.
2.Used in the synthesis of highly substituted chiral v-lactams via catalytic asymmetric formal [3+2][3+2]- and [3+3]-cycloadditions of(Z)-v-ethyI enoldiazoacetate with diaziridine.